API API-571 - Corrosion and Materials Professional

According to API RP 571, under the section on High Temperature Hydrogen Attack (HTHA) and Decarburization:

“Decarburization is typically confirmed by metallographic examination. This method reveals carbon loss and microstructural changes such as spheroidization or softening of pearlite.”

“Tensile or impact testing may not reveal early-stage decarburization, especially in partial layers.”

Therefore, metallographic testing is the standard and most direct method to confirm decarburization damage, making option D correct.

API RP 571 – Polythionic Acid Stress Corrosion Cracking:

“Polythionic acid SCC may be mistaken for wet H₂S damage because both involve cracking in austenitic stainless steels under certain conditions.”

Thus, option D is correct.

According to API RP 571 Section 5.2.1 (Fatigue – High Cycle and Low Cycle):

“Unsupported small-bore attachments like vents and drains are prone to high-cycle mechanical fatigue due to vibration. These attachments experience cyclic stress, especially near welds or bends.”

Thermal overload is unlikely without over-temperature data.

SSC (Option C) requires a wet H2S environment, which is not indicated.

Weld defects may contribute but are less likely the root cause without other signs.

Hence, mechanical fatigue (Option A) is most probable in this configuration.

API RP 571 provides detailed insights:

“Brittle fracture generally occurs at low temperatures, specifically below the ductile-to-brittle transition temperature as defined by the Charpy impact test.”

“Most carbon and low-alloy steels are ductile above their Charpy transition temperature but may fracture suddenly without ductility below it.”

(Reference: API RP 571, Section 4.2.1.2 – Brittle Fracture)

Hence, option C is correct and technically accurate based on the material behavior curve.

API RP 571 notes that for detecting existing cracks or flaws that may lead to brittle fracture, especially those that initiate at welds or surface stress points:

“Wet fluorescent magnetic-particle inspection is highly effective for detecting surface-breaking flaws in ferromagnetic materials that are susceptible to brittle fracture.”

“It is sensitive to tight cracks and surface discontinuities that may serve as initiation sites for brittle fracture.”

(Reference: API RP 571, Section 4.2.1.2 – Brittle Fracture)

Therefore, option A is correct as it is the most effective NDE technique for detecting early signs of brittle cracking.

API RP 571 discusses Hydrogen-Induced Cracking (HIC) and Blistering:

“Postweld heat treatment (PWHT) does not significantly reduce susceptibility to HIC, as the mechanism is primarily driven by hydrogen charging in wet H₂S environments and steel cleanliness, not residual stresses.”

“PWHT is more effective for SSC, SOHIC, and other stress-driven mechanisms.”

Thus, HIC will not benefit much from PWHT, making option C correct.

As per API RP 571 Section 5.3.2.3 (Spheroidization):

“Spheroidization is the transformation of the microstructure of steels into spherical carbides, leading to reduced strength and hardness, especially after extended high-temperature exposure. It’s commonly seen in carbon and low alloy steels in refining heaters and reactors.”

It reduces strength and sometimes hardness.

It increases ductility, not reduces.

SCC potential is not directly tied to this change.

Therefore, Option D (Loss of strength) is correct.

API RP 571 under Oxidation states:

“Resistance to oxidation is improved significantly by increasing chromium content, as it promotes the formation of a protective chromium oxide (Cr₂O₃) layer.”

“Nickel may aid in high-temperature strength but does not directly improve oxidation resistance like chromium does.”

(Reference: API RP 571, Section 5.1.1 – Oxidation)

Hence, option A is correct.

According to API RP 571, under Caustic Stress Corrosion Cracking (Caustic Embrittlement):

“Cracking occurs in stressed components exposed to caustic (e.g., sodium hydroxide).”

“The most effective mitigation strategy is postweld heat treatment (PWHT), which relieves residual stress that promotes cracking.”

“Upgrading materials or controlling concentration may help, but do not replace stress relief.”

(Reference: API RP 571, Section 4.2.2.3 – Caustic SCC)

Thus, PWHT is the most effective prevention technique, making option A correct.

API RP 571 defines Hydrogen Embrittlement as:

“Improper PWHT can trap hydrogen within the microstructure of carbon steel or fail to relieve residual stresses, both of which increase the risk of hydrogen embrittlement.”

“Moisture in electrodes contributes to hydrogen-induced cracking, but embrittlement from atomic hydrogen is more directly tied to heat treatment and microstructure.”

Thus, option D is the most accurate.